Hexaaquacobalt(II) tetraaquabis(2-aminopyrazine-κN4)cobalt(II) disulfate dihydrate

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Bis(2,6-diamino­pyridin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate

In the title compound, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete complex cation is generated by crystallographic inversion symmetry, such that the Co(II) cation is octa-hedrally coordinated by six water mol-ecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and mol-ecules are linked into a pseudo-lay...

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Bis(2-amino-4-methyl­pyrimidin-1-ium) hexa­aqua­cobalt(II) disulfate dihydrate

In the title hydrated mixed-cation salt, (C(5)H(8)N(3))(2)[Co(H(2)O)(6)](SO(4))(2)·2H(2)O, the complete octa-hedral hexa-aqua complex cation is generated by crystallographic inversion symmetry. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, the latter, involving pyrimidinium cations and sulfate anions, generating R(2) (2)(8) loops. These, together with π-π inter-ac...

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Hexaaqua­cobalt(II) tetra­aqua­bis(2-amino­pyrazine-κN 4)cobalt(II) disulfate dihydrate

The reaction of cobalt(II) sulfate and 2-amino-pyrazine affords the title salt, [Co(H(2)O)(6)][Co(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra-aqua-coordinated and hexa-aqua-coordinated complex cations lie on centers of inversion in slightly distorted octa-hedral geometries. The cations, anions and solvent water mol-ecules are linked by O-H⋯O, O-H⋯N and N-H⋯O hydro...

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Hexaaqua­manganese(II) tetra­aqua­bis(2-amino­pyrazine-κN 4)manganese(II) disulfate dihydrate

The reaction of manganese(II) sulfate and 2-amino-pyrazine affords the title salt, [Mn(H(2)O)(6)][Mn(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra-aqua-coordinated and hexa-aqua-coordinated cations lie on centers of inversion in octa-hedral geometries. The cations, anions and solvent water mol-ecules are linked by O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonds into a three-d...

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The crystal structure of guanosine dihydrate and inosine dihydrate.

Crystals of the dihydrates of guanosine (C10H13NsOs) and inosine (C10H12N405) are nearly isostructural. They are monoclinic, space group P21, with cell dimensions a= 17·518, b= 11 ·502, c= 6·658 A, P=98·17° (guanosine) and a=17·573, b=11·278, c=6-654A, P=98·23° (inosine). There are two nucleoside molecules and four water molecules per asymmetric unit. Data were collected on an automated diffrac...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809045310